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GSH functions as a signaling molecule which activates the breast cancer stem cell phenotype through copper chelation that leads to an inhibition of mitogen-activated protein kinase kinase (MEK) activity, leading to inactivation of MEK1-ERK signaling, FoxO3 dephosphorylation, and nuclear translocation ultimately leading to enrichment of breast cancer stem cells [158] High ROS production in cancer cells requires high activity of cellular antioxidant systems making cancer cells hypersensitive to exogenous agents that damage their antioxidant capability

By promoting detoxification, glutathione helps maintain the proper functioning of vital organs like the liver and kidneys, which are responsible for filtering and eliminating waste products from the bloodstream

The use of GSH-AuNCs as probes in conjunction of fluorescence and X-ray computed tomography (CT) imaging platforms has been reported in vitro and in vivo 17,19

FEBS Letters 596, 29893004